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Microcalorimetry of macromolecules download pdf

Dedicated to the memory of Professor Julian Sturtevant. It is shown that the predenaturational changes of proteins must not be ignored in studying the thermodynamics of formation of their native structure and their complexes with partners, particularly their cognate DNA duplexes. Check if you have access microcalorimetry of macromolecules download pdf your login credentials or your institution. Microcalorimetry was applied for determining curing kinetics of HTPB binder system.

The detailed thermokinetics analysis of HTPB-DOS-PAPI binder system was achieved. The thermodynamic properties of HTPB-DOS-PAPI binder system was obtained. The model function to accurately describe the curing behavior was obtained. The curing was completed after 5. Thus, a shorter time was required to complete curing at a higher temperature. The curing reaction was exothermic, and temperature had minimal effect on the values of the total reaction heat within the testing temperatures. Therefore, the title reaction was non-spontaneous.

The effect of plasticizer on curing kinetics has also been investigated. It was found that the reaction rate constants and total reaction heat decreased with the increase of DOS contents. The thermodynamic properties of the reaction were studied by varying the content of PAPI at 323. The curing reaction of the HTPB-DOS-PAPI binder system at 323.

Dedicated to the memory of Professor Julian Sturtevant. It is shown that the predenaturational changes of proteins must not be ignored in studying the thermodynamics of formation of their native structure and their complexes with partners, particularly their cognate DNA duplexes. Check if you have access through your login credentials or your institution. Microcalorimetry was applied for determining curing kinetics of HTPB binder system. The detailed thermokinetics analysis of HTPB-DOS-PAPI binder system was achieved. The thermodynamic properties of HTPB-DOS-PAPI binder system was obtained. The model function to accurately describe the curing behavior was obtained.